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Q.

Which of the following is not a Lewis acid ?

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a

SnCl4

b

AlCl3

c

AlCl3.6H2O

d

FeCl3

answer is D.

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Detailed Solution

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A Lewis acid is characterized by its ability to accept at least one lone pair using an empty orbital of right energy. AlCl3, SnCl4, and FeCl3 act as Lewis acids because of the ability of their central atoms to accept lone pairs in their empty orbitals. AlCl3.6H2O or [Al(H2O)6]Cl3 cannot act as a Lewis acid because the central ion Al3+ is no longer in a position to accept the lone pair as its coordination number is fulfilled.

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