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Q.

Which of the following is not a possible de-Broglie's wavelength of a particle, which moves inside a cubical box of side length L, without losing any energy (elastically colliding with walls of cube)?

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a

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b

All of these

c

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d

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answer is D.

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Detailed Solution

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Using concept of stationary waves, we can say at rigid walls Node formation takes place.

L=λ2, λ, 3λ2, 2λ..., nλ2 where n=1,2,3... 

Longest wavelength is specified by λ=2L. next by λ=L
then λ=L×23. etc 
 In general λn=2Ln,n=1,2,3,
For(a) λ=2L3
For (b) λ=L
For (c) )λ=2L . Hence, all are possible.

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