Which of the following is not an intramolecular redox reaction?

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${NH}_{4} {NO}_{2} ⟶ N_{2} + 2 H_{2} O$

$2 {KClO}_{3} ⟶ 2 KCl + 3 O_{2}$

$2 H_{2} O_{2} ⟶ 2 H_{2} O + O_{2}$

$2 {Mn}_{2} O_{7} ⟶ 4 {MnO}_{2} + 3 O_{2}$

answer is D.

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Detailed Solution

Intramolecular redox change involves oxidation of one atom and reduction of the other atom within a molecule. hydrogen peroxide reaction is disproportionation reaction but not intramolecular, because only oxygen undergoing both oxidation and reduction.

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