Q.

Which of the following is not correct w.r.t. covalent character of ionic bond? 

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a

For same size and charge of cation, the one with electronic configuration n-1dxns0 is more polarising than the cation having ns2np6 electronic configuration.

b

Cation polarises the anion.

c

Electronic charge shifts towards cation to create covalent character.

d

Smaller the charge on cation and anion, greater is the covalent character.

answer is D.

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Detailed Solution

Covalent character in ionic bond increases with increase in charge on cation and anion.

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