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Q.

Which of the following is not correctly matched?

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a

Fe(CO)2NO+2sp3 and diamagnetic

b

Fe(en)33+sp3d2 and paramagnetic

c

FeCl42sp8 and paramagnetic

d

Fe(CN)63d2sp3 and paramagnetic

answer is A.

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Detailed Solution

Since Fe(en)33+ has 5 electrons in its d orbital [Ar]3d5 it has low spin.

Hence correct option is A.

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