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Q.

Which of the following is not tetrahedral?

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a

BF4-

b

NH4+

c

CO32-

d

SO42-

answer is C.

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Detailed Solution

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1) BF4-

H = 1/2 [V + M - C + A]

= 1/2 [3 + 4 - 0 + 1]

= 1/2 [8] = 4 ⇒ sp3 ⇒ Tetrahedral

2) NH4+

H = 1/2 [5 + 4 - 1 + 0]

= 8/2 = 4 ⇒ sp3 ⇒ Tetrahedral

3) CO32-

H = 1/2 [4 + 0 - 0 + 2]

= 6/2 = 3 ⇒ sp2 ⇒ Trigonal planar

4) SO42- 

H = 1/2 [6 + 0 - 0 + 2]

= 8/2 = 4 ⇒ sp3 ⇒  Tetrahedral.

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