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Q.

Which of the following is not the property of homologous series?

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a

They can be represented by a general formula. 

b

They differ by -CH2 unit.

c

They all contain double bond

d

They differ by 14 units by mass

answer is C.

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Detailed Solution

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  • They all contain double bonds that are not the property of homologous series.
    A homologous series is defined as a series of compounds that are similarly constituted and the members present have the same functional group and similar chemical properties.
  • Any two succeeding members of a specific series can be distinguished by a -CH2 unit in terms of their molecular formula. 
  • The two adjacent homologues differ by 1 carbon atom and 2 hydrogen atoms in their molecular formulas. 
  • The difference in the molecular masses of any two adjacent homologues or members is 14u. 
  • A gradual change in the physical properties is seen because of the increase in the molecular masses. 
  • For example, melting and boiling points increase with the increasing molecular mass. 
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