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Q.

Which of the following is not true

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a

Ordinary water is electrolysed more rapidly than D2O

b

Reaction between H2 and Cl2 is much faster than D2 and Cl2

c

D2O freezes at lower temperature than H2O

d

Bond dissociation energy for D2 is greater than H2

answer is C.

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Detailed Solution

Physical Constants : D2O > H2O

Reason, Due to high molecular weight of D2O[20] than  that of H2O.

Molecular mass Physical constants

Exception Dielectric constant (D)

[Dielectric const] D : H2O > D2O

→ Ordinary water is electrolysed more rapidly than D2O

Reason ; Dielectric constant of water [DH2O] > Dielectric constant of D2O[DD2O]

Note : Dielectric constant is the ability of a solvent to ionise the bond of a salt.

Higher the dielectric constant higher will be the ionisation ability.

→ Bond Dissociation energy :

large xrightarrow{D_2 ;>;H_2}

As bond dissaciation energy ↓es reactivity with Cl2 ↑es.

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