Q.

Which of the following is tetrahedral paramagnetic complex ?

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a

K2HgI4

b

K2ZnCl4

c

K2MnCl4

d

K2PtCl4

answer is B.

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Detailed Solution

K2PtCl4 Diamagnetic square planar d8, SFL, C.N.=4
K2MnCl4 Paramagnetic tetrahedral d5, WFL, C. N.=4
K2ZnCl4 Diamagnetic tetrahedral d10,C.N.=4
K2HgI4 Diamagnetic tetrahedral d10,C.N.=4

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