Q.

Which of the following is the condition for a non spontaneous reaction at high temperature but spontaneous at low temperature?

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a

ΔH=+ve,ΔS=+ve

b

ΔH=-ve,ΔS=-ve

c

ΔH=-ve,ΔS=+ve

answer is A.

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Detailed Solution

 Change in Gibbs free energy equation

ΔG=ΔH-TΔS

Where, ΔH is change in enthalpy and ΔS is change in .

ΔG=+ve for non-spontaneous

ΔG=0 for equilibrium

ΔS>0,ΔH<0 for spontaneous.

When ΔH<0 and ΔS<0 then ΔG=-ve at low temperature and the reaction become spontaneous.

Therefore, option A is correct.

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