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Q.

Which of the following is the correct order of ionisation energy?

(1) Be+>Be      (2) Be>Be+    (3) C>Be     (4) B>Be  

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a

1, 3

b

2, 3

c

3, 4

d

None of these

answer is C.

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Detailed Solution

(1) Be possesses a fully filled stable v configuration, or 2s2, whereas Be+ positive charge makes the removal of an electron far more energy-intensive. Therefore, Be+ionisation energy is higher than Be.

(3) As atomic size falls and nuclear size rises during the course of the period, the nucleus tightly holds the electron(s) from the valence shell. Ionisation energy is therefore larger than Be.

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