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Q.

Which of the following is the correct statement for PH3?

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a

It is less basic than NH3

b

It is less poisonous than NH3

c

It does not show reducing properties

d

None of the above

answer is A.

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Detailed Solution

The atom of nitrogen is more electronegative than the atom of phosphorus. The bound pair of electrons between the N and H atoms are drawn to the nitrogen in NH3, and this action is stronger in NH3 than in PH3. As a result, the lone pair of electrons in NH3 can participate in the dative bonding to a greater extent than those in PH3.

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