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Q.

Which of the following is the correct CFSE configuration for [CoCl4]2- complex:

[p = Pairing energy]

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a

1.2 + 2p

b

0.8 + 2p

c

 1.2 + 2p

d

0.8 + 2p

answer is B.

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Detailed Solution

 [CoCl4]2-   Co  [Ar]3d74s2  Co+2 [Ar]3d7

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CFSE = 0.6 eges- +0.4 t2g es-+ mp           =  0.6 × 4 + 0.4 × 3 + 2p          = 1.2 + 2p

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