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Q.

Which of the following is the most stable, and which is the next most stable isomer?

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a

I > III

b

III > I

c

IV > III

d

II > I

answer is A.

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Detailed Solution

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(Both have conjugated system)
In (II) 3α-H atom but have isolated system.
In (IV) 2-α-H atom & conjugated system but strained ring due
to (C=C) bond outside ring.
.'. stability order:
III > I > II > IV

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