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Q.

Which of the following is true for magnesium ?

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a

It is more electropositive than sodium

b

It is manufactured by electrolysis of aqueous magnesium chloride

c

It is strong reducing agent

d

It resembles, in chemcial properties, with its diagonally placed element boron in 13 group of the periodic table

answer is C.

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Detailed Solution

  1. Electropositivity order
     
Question Image
  1. Mg is not extracted by the electrolysis of aqueous MgCl2
    Reason
     
large MgC{l_2};xrightarrow{{Electrolysis}};M{g^{ + 2}}; + ;2mathop {Cl}limits^ ominus

  1. Oxidation potential order of anion :
large C{l^ ominus }; > ;Omathop Hlimits^ ominus

  1. Similary reduction potential order for cations : H+ > Mg+2
     
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  1.  
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  1.  
large M{g^{ + 2}}; + ;2mathop {OH}limits^ - ; to ;Mg{left[ {OH} right]_2}

  1. Products are : Cl2 , H2 , Mg(OH)2
  2. Mg strong reducing agent than H2
  3. Diagonal relationship exists between the elements of 2rd period with 3rd period next group
     
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