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Q.

Which of the following is true for the complex CoNO2(Cl)25NH3( Co is in+ III oxidation state)?

 

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a

 It shows linkage isomerism

b

 If is inner orbital complex

c

 It show ionisation isomerism

d

It is diamagnetic.

answer is A, B, C, D.

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Detailed Solution

CoNH35NO2Cl2 and CoNH35ClClNO2 are ionisation isomers.

CoNH35NO2Cl2 and CoNH35(ONO)Cl2 are linkage isomers.

The 3d6 structure of cobalt in the +3 oxidation state has a higher CFSE. The complex is hence diamagnetic and in the inner orbital state (i.e.d2sp3hybridisation).

Thus, all options are true for the given complex.

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