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Q.

Which of the following is/are correct for potassium ferrocyanide?

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a

It gives a brown precipitate with Cu2+  ions.

b

It develops a deep red colouration with Fe3+

c

It in excess gives a bluish white/white precipitate with Zn2+

d

It gives a white precipitate 9f mixed salt with Ca2+ ions.

answer is A, B, C.

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Detailed Solution

Potassium ferrocyanide,

K4Fe(CN)63 (Prussian blue)

It gives a brown precipitate with Cu2+ ions.

K4Fe(CN)63+Cu2+Cu2Fe(CN)6Raddish-Brown ppt

It gives a white precipitate 9f mixed salt with Ca2+ ions.

FeC(N)64+Ca2+NH4ClCaNH4KWhite pptFe(CN)66

It in excess gives a bluish white/white precipitate with Zn2+

Thus, options  A, B and C are correct .

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