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Which of the following is/are correctly matched?

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CoPMe34sp3 and one unpaired electron.
Ni(en)3NO22sp3d2 and two unpaired electrons.
VNH36Cl3sp3d2 and two unpaired electrons.
MnNO+3(CO)sp3 and diamagnetic.

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detailed solution

Correct option is A

The hybridization of CoPMe34sp3 is and in this, the unpaired electron is 1.

The hybridization of Ni(en)3NO22sp3d2 is and in this, the unpaired electron is 2.

The hybridization of  MnNO+3(CO)sp3 is and in this, the unpaired electron 1 and diamagnetic.

Hence, the correct option is a, b and d. 

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