Q.

Which of the following isomer of pentane C5H12 will give three isomeric monochlorides on photochemical chlorination?(stuctural isomers only)

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a

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b

CH3CH2CH2CH2CH3

c

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d

All of the above

answer is B.

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Detailed Solution

n - pentane on mono chlorination forms :

1-chloro  pentane

2-chloro pentane (optically active )

3 -chloro pentane

including stereo isomers 4 isoers are possible. 

excluding stereo isomerism 3 isomers are possible which are structural isomers

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