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Q.

Which of the following isomerism, exhibited by octahedral CoNH34Br2Cll?

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a

Geometrical and ionization

b

Geometrical and optical

c

Optical and ionization

d

Geometrical only

answer is A.

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Detailed Solution


[Co(NH3)4Br2]Cl complex

  • In Co(NH3)4Br2Cl, center metal cobalt is in a +3 oxidation state.
  • Co(NH3)4Br2Cl has ionization isomers.
  • This isomerism occurs due to the interchange of ions between the inner and the outer coordination sphere.
  • Ionization isomers can be written as:

Co(NH3)4Br2Cl and Co(NH3)4BrClBr

  • This isomerism comes as a result of ion exchange between the inner and outer coordination spheres.
  • Although it can form geometric isomers, cis and trans, neither is optically active.
  • Structure are as follows:
     
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