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Which of the following is ${sp}^{3} d$ hybridized as well as as trigonal bipyramidal geometry?

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${SF}_{4}$

${PCl}_{5}$

${XeF}_{2}$

${ClF}_{3}$

answer is B.

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Detailed Solution

Phosphorus contains 5 electrons of valence. Therefore, PCl₅ molecules have sp³d hybridization and therefore a trigonal bipyramidal structure, 1 electron each is shared by chlorine atom.

${PCl}_{5}$ is ${sp}^{3} d$ as well as TBP geometry.

Hence, the correct option is B.

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