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Q.

Which of the following liquid pairs shows a positive deviation from Raoult's law?

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a

water-hydrochloric acid

b

benzene-methanol

c

water-nitric acid

d

acetone-chloroform

answer is B.

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Detailed Solution

The molecular interactions between benzene and methanol are weaker than those existing between benzene and benzene, and methanol and methanol. Consequently, the solution will exhibit positive deviations from Raoult's law.

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