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Q.

Which of the following metal oxide is more stable if the free energies of formation of Cr2O3, and  Al2O3 per mole of oxygen consumed are -540 kJ and -827 kJ respectively?

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a

Both have equal stability

b

Al2O3

c

None of the above

d

Cr2O3

answer is B.

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Detailed Solution

Aluminium oxide is stable if the free energies of the formation of  Cr2O3,and Al2O8 per mole of oxygen consumed are -540 kJ and -827 kJ respectively.

According to the Ellingham diagram, a metal's stability in the form of its oxide increases with the location of the metal line; the lower the metal line, the more negative the Gibbs free energy, and the more stable the metal will be.

Hence the correct option is B

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