Which of the following methods is used to prepare Aniline on large scale ?
A) $C_{6} H_{5} {NO}_{2} + 6 (H) \overset{Fe / HCl}{⟶} C_{6} H_{5} {NH}_{2} + 2 H_{2} O$
B) $C_{6} H_{5} {NO}_{2} + 6 (H) \overset{Sn / HCl}{⟶} C_{6} H_{5} {NH}_{2} + 2 H_{2} O$
C) $C_{6} H_{5} {OH}_{2} + {NH}_{3} \frac{{ZnCl}_{2}}{300^{\circ} C} C_{6} H_{5} {NH}_{2} + H_{2} O$
D) $C_{6} H_{5} Cl + 2 {NH}_{3} \overset{{Cu}_{2} 200^{\circ} C}{⟶} C_{6} H_{5} {NH}_{2} + {NH}_{4} Cl$

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A only

B or C

C only

A or D

answer is A.

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Detailed Solution

A $C_{6} H_{5} {NO}_{2} + 6 (H) \overset{Fe / HCl}{⟶} C_{6} H_{5} {NH}_{2} + 2 H_{2} O$ -method is industrial method

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