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Q.

Which of the following mixture shows negative deviation from Raoult’s law ?

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a

$C_{2} H_{5} C l$ and $C_{2} H_{5} B r$

b

$C H C l_{3}$ and $C H_{3} C O C H_{3}$

c

$C_{6} H_{5} C H_{3}$ and $C_{6} H_{6}$

d

$C_{6} H_{6}$ and $C_{2} H_{5} O H$

answer is A.

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Detailed Solution

The solution whose vapour pressure is less than Raoult’s vapour pressure are said to show negative deviation from Raoult’s law.

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