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Q.

Which of the following mixtures cannot be separated by fractional distillation?

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a

Chloroform and benzene

b

H2, CH4, liquid natural gas

c

Acetone and methyl alcohol

d

Benzene and toluene

answer is C.

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Detailed Solution

Fractional distillation method is used for separation of substances whose boiling point difference must be below 25°C. H2, CH4 and liquid natural gas is a cryogenic mixture and it has high boiling point. Thus, fractional distillation method is not suitable for separating the components to individuals from the mixture.

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