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Q.

Which of the following mixtures will show positive deviation from Raoult's law?

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a

Ethanol and Water

b

Chloroform and Acetone

c

HCl and Water

d

Benzene and Toluene

answer is A.

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Detailed Solution

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  • A mixture of ethanol and water shows positive deviation from Raoult's law.  
  • The intermolecular forces present are weaker than those present in the ideal solution. 
  • The total vapor pressure of the solution is greater than the total vapor pressure of an ideal solution. 
  • Also, the vapor pressure of each component is greater than that predicted from Raoult's law.
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Which of the following mixtures will show positive deviation from Raoult's law?