Which of the following molecule has the highest value of dipole moment?

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${PF}_{2} {Cl}_{3}$

${PBr}_{3} {Cl}_{2}$

${PCl}_{5}$

${PCl}_{2} F_{3}$

answer is D.

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Detailed Solution

In $P C l_{2} F_{3},$ F atoms are present in axial as well as equatorial positions. So it is unsymmetrical and the dipole vectors are not cancelled. Therefore it's dipole moment is non zero. Other molecules have zero dipole moments.

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