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Q.

Which of the following molecules/ions can exhibit isomerism?


A) Tetrahedral        NiCl2Br22-
B) Squareplanar     PtNH32Cl2
C) Octahedral       CoNH36Cl3
D) Squareplanar    PdNH33Br+

E) Octahedral  Co(en)33+

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a

B, C, E

b

A, B, C, D

c

B, C, D

d

A, B, C, E

answer is B.

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Detailed Solution

  • Tetrahedral compounds do not exhibit isomerism because the unidentate ligands linked to the central atom are in the same relative positions to one another. compounds of type square planar Ma2b2 shows geometric isomerism.
  • Octahedral compounds of type Ma3b3 shows geometric isomerism and of type M(AA)3 optical isomerism is present.
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Which of the following molecules/ions can exhibit isomerism?A) Tetrahedral        NiCl2Br22-B) Squareplanar     PtNH32Cl2C) Octahedral       CoNH36Cl3D) Squareplanar    PdNH33Br+E) Octahedral  Co(en)33+