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Q.

Which of the following option is correct for FeH2O62+ and CoH2O63+?

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a

both have same magnetic moment

b

both are high spin complex

c

Δ0>P for both

d

Splitting gap is different in both

answer is D.

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Detailed Solution

CoH2O62+ is diamagnetic and Δ0>P.

FeH2O62+ is paramagnetic and  Δ0<P.

Because of the different coordination number, size of a metal atom, ligand arrangement, and charge on the metal atom, both compounds have the different splitting gap. Hence splitting gap is different in FeH2O62+ and CoH2O63+.

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