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Q.

Which of the following option(s) is/are true?

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a

If the compound contains N, S and Halogen they get converted into soluble sodium salts in the preparation of sodium fusion extract.    

b

The presence of the Chlorine in the Compound can not be confirmed with Lassaigne’s Test

c

When (CH3COO)4Pb solution is added to the acidified Lassaigne’s extract of an organic compound containing S, a black precipitate of PbS is formed

d

To the sodium extract, cold.dil. HNO3  should be added before treating with  AgNO3 to detect the halogen if the compound has N or S.

answer is A, B, C, D.

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Detailed Solution

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A) AgCl is not detectable if AgI  is present
B) Fluorides are soluble
C & D) by boiling HCN and H2S  will escape from the test tube

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