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Q.

Which of the following option will be the limiting molar conductivity of CH3COOH if the limiting molar conductivity of CH3COONa is 91Scm2mol1? Limiting molar conductivity for individual ions are given in the following table.

S.NoIons

limiting molar

 conductivity / Scm2mol1

1H+349.6
2Na+50.1
3K+73.5
4OH199.1

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a

340.4 Scm2mol1

b

390.5 Scm2mol1

c

375.3 Scm2 mol1

d

350 Scm2 mol1

answer is C.

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Detailed Solution

The limiting molar conductivity mo  for strong and weak electrolyte can be determined by using Kohlrausch's law which states that "the limiting molar conductivity of an electrolyte can be represented as the sum of the individual contributions of the anion and cation of the electrolyte."

CH3COONa=CH3COO-+ Na+

91Scm2mol1=CH3COO+50.1Scm2mol1

CH3COO-=40.9Scm2mol1

For acetic acid,

CH3COOH=CH3COO-+H+                  =40.9Scm2mol1+349.6Scm2mol-1                    =390.5Scm2mol-1

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