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Q.

Which of the following order is correct among
the following ?
I)  C–X Bond length order is   H3C–F < H3C –Cl < H3C–Br < H3C–I
II)  C–X Bond enthalpies order is  H3C–F > H3C –Cl > H3C–Br > H3C–I
III) C–X Bond dipole moment order is   H3C–Cl > H3C–F > CH3–Br > CH3–I

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a

All are correct

b

Only I & II

c

Only I & III

d

Only II & III

answer is D.

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Detailed Solution

  • As the size of halogen atom increases, the C−X bond length increases and hence, the C−X bond strength decreases. 
  • Bond length 1B.E
  • Order of dipole moment based on E.N of halogen and bond length of    C-X bond.

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