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Q.

Which of the following order is correct for boiling point?

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a

NH3>PH3

b

CH3OCH3>C2H5OH

c

o-hvdroxvbenzaldehyde > m-hydroxybenzaldehyde

d

None of the above

answer is A.

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Detailed Solution

Phosphine PH3 has a lower boiling point than ammonia .NH3

Strong intermolecular hydrogen bonds betweenNH3  molecules are formed. However, bigger PH3 molecules cannot establish hydrogen bonds amongst themselves due to their lower electronegativity. Unlike PH3, where hydrogen bonds are absent, NH3 does have hydrogen bonds. NH3 has a greater boiling point than PH3 as a result.

Hence, option A is correct.

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