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Q.

Which of the following order is correct for strength and extent of H-bonding between H2O and H2O2 respectively:

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a

H2O<H2O2 and  H2O>H2O2

b

H2O>H2O2 and H2O2<H2O

c

H2O>H2O2 and H2O2>H2O

d

H2O<H2O2 and H2O<H2O2

answer is C.

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Detailed Solution

The strength of H-bonding is greater in H2O than in H2O2  because water has more formal negative charge on the oxygen atom than H2O2.
Because of the largest electronegativity difference between H and F, HF has the strongest hydrogen bond. The hydrogen molecule is covalently bonded and does not exhibit hydrogen bonding.
As a result, the order is HF>H2O>H2O2>H2.

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