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Q.

Which of the following order is incorrect among the following ?

I) C-X Bond length order is H3C-F<H3C-Cl<H3C-Br<H3C-I

II) C-X Bond enthalpies order is H3C-F>H3C-Cl>H3C-Br>H3C-I

III) C-X Bond dipole moment order is H3C-Cl<H3C-F<CH3-Br<CH3-I

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a

Only I & III 

b

Only I & II 

c

Only III

d

Only II & III

answer is D.

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Detailed Solution

  • The polarity of the C-X bond is projected to rise when the electronegativity gap between carbon and halogen atoms increases. 
  • Haloarenes have polarized C-X bonds because halogens are more electronegative than carbon. Halogen draws the electron cloud more toward itself because of its strong electronegativity, giving it a slight negative charge, while carbon receives a slight positive charge.
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