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Q.

Which of the following order is incorrect among the following?                      

         I) C-X Bond length order is

               H3CF<H3CCl<H3CBr<H3CI

         II) C-X Bond enthalpies order is

                H3CF>H3CCl>H3CBr>H3CI

         III) C-X Bond dipole moment order is

                H3CCl<H3CF<CH3Br<CH3I

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a

Only I & II  

b

Only II & III      

c

Only I & III    

d

Only III

answer is D.

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Detailed Solution

  • As the size of halogen atom increases, the C−X bond length increases and hence, the C−X bond strength decreases. 
  • Bond length α1B.E
  • Order of dipole moment based on E.N of halogen and bond length of C-X bond.
  • CH3Cl>CH3F>CH3Br>CH3I
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