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Q.

Which of the following order ls correct with respect to the given property?

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a

HClO<HClO2<HClO3<HClO4 (acidic strength)

b

B2O3<Al2O3<Ga2O3<In2O3<Tl2O (acidic nature)

c

F<Cl<Br<I (basic nature)

d

HF<HCl<HBr<HI (thermal stability)

answer is A.

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Detailed Solution

Stability of conjugate base is ClO<ClO2<ClO3<ClO4.

Chlorine is less electronegative than oxygen. More electrons are drawn away from the OH bond and the OH connection weakens as the number of O atoms connected to Cl rises. The acid's potency is boosted by this.
The list of acids in decreasing order of acidity is HClO4>HClO3>HClO2>HClO.

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Which of the following order ls correct with respect to the given property?