Which of the following order regarding the rate of alkaline hydrolysis of esters is correct?

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${CH}_{3} {COOCH}_{3} > {CH}_{3} {COOC}_{2} H_{5} > C_{2} H_{5} {COOC}_{2} H_{5}$

${CH}_{3} {COOCH}_{3} < {CH}_{3} {COOC}_{2} H_{5} > C_{2} H_{5} {COOC}_{2} H_{5}$

${CH}_{3} {COOCH}_{3} > {CH}_{3} {COOC}_{2} H_{5} < C_{2} H_{5} {COOC}_{2} H_{5}$

${CH}_{3} {COOCH}_{3} < {CH}_{3} {COOC}_{2} H_{5} < C_{2} H_{5} {COOC}_{2} H_{5}$

answer is A.

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Detailed Solution

Order ${CH}_{3} {COOCH}_{3} > {CH}_{3} {COOC}_{2} H_{5} > C_{2} H_{5} {COOC}_{2} H_{5}$ regarding the rate of alkaline hydrolysis of esters is correct.

With increase in the bulkiness of R and R' group in RCOOR', the alkaline hydrolysis becomes slower.

Hence, option A is correct.

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