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Q.

Which of the following order(s) is correct

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a

Question Image (Basic nature)

b

All the above

c

HCOOH>CH3COOH (Acidic nature)

d

 Question Image(Basic nature)

answer is D.

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Detailed Solution

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(A) Cyclohexylamine is a stronger base than aniline because in aniline electron pair is involved in conjugation, which makes the electron pair unavailable, where as in cyclohexyl amine, the −NH2 group is out side the ring and there is no resonance in the ring also, thereby the lone pair present on the nitrogen is freely available, resulting in a stronger base.

(B) due to +I effect

(C) Lone pair on 'N' is readily available in fist one than other due to absence of pyramidal inversion.

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