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Q.

Which of the following overlaps is incorrect (assuming the Z-axis is internuclear axis)?

(A) 2py+2pyπBond formation

(B)  2px+2pxσBond formation

(C) 3dxy+3dxyπBond formation

(D) 2s+2pyπBond formation

(E) 3dxy+3dxyδBond formation

(F) 2pz+2pzσBond formation

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a

A, B, C

b

B, C, D

c

C, F

d

B, E

answer is D.

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Detailed Solution

π bonds are covalent chemical bonds where two lobes of an orbital in an atom orbital two lobes of an orbital on another atom & this over lop occurs bterally 4 perpendicularly to internuclear axis
Delta bonds are formed by sideways overlap of 4 lobes of d-orbitals perpendicular to internuclear axis.
B) In (B), 2px orbitals are perpendicular to z-axis 4 should more π bond.
C) In (C), 3dxy are perpendicular to z axis 4. should more delta bond
D) In (D) 2s, (s- orbital) only make sigma bonds.

Hence, the option D is correct.

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