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Q.

Which of the following oxide(s) gives brown ppt on reaction with conc. HNO3 ?

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a

Pb3O4

b

SnO

c

PbO

d

Pb2O3

answer is C, D.

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Detailed Solution

PB3O4 gives brown ppt when react with conc. HNO3. The reaction is.

Pb3O4+4HNO32Pb(NO3)2+PbO2+2H2O

Also, Pb2O3 gives brown ppt when react with conc. HNO3.

Thus, C and D are correct.

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