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Q.

Which of the following pair of ions can not be separated by H2S  and dil. HCl 

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a

Bi+3,Sn+4

b

Al+3,Hg+2

c

Zn+2,Cu+2

d

Ni+2,Cu+2

answer is A.

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Detailed Solution

Bi+3 and Sn+4both will form ppt with H2S ; Bi+3+S2Bi2S3(Orange PPt)
Sn+4+S2SnS2(Dirty yellow PPt)
Al+3,Zn+2 and Ni+2will not form ppt with H2S in acidic medium

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