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Q.

Which of the following pairs of elements  have nearly same atomic radii due to lanthanide contraction ? (Numbers in the parenthesis are atomic numbers)

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a

Zr(40) and Hf(72)

b

Zr(40) and Ta(73)

c

Ti(22) and Zr(40)

d

Zr(40) and Nb(41)

answer is A.

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Detailed Solution

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Zr(40) and Hf(72) have nearly same radii due to lanthanoid contraction.
Between these two elements, Lanthanoids (Z=58-71) are present. In lanthanoids, poor screening of 4f orbitals leads to contraction in size. Due to this, Zr-Hf….Nb-Ta…Mo-W…will have nearly same size.

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