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Q.

Which of the following pairs of the compounds will produce blood red color in the Lassaigne's test for nitrogen?

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a

Urea and thiourea

b

Thiourea and p - sulphanilic acid

c

Benzene sulphonic acid and aniline

d

Aniline and thiourea

answer is B.

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Detailed Solution

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When nitrogen and sulphur both are present in the organic compound, they combine during fusion to form sodium thiocyanate (sulphocyanide), This when heated with FeSO4 ​or FeCl3​, produces a red blood colouration due to ferric thiocyanate (or sulphocyanide).

Thus, thioureaThiourea, and p-sulphanilic acidImage result for p-sulphanilic acid give red colour on Lassaigne test.

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