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Q.

Which of the following pairs represents linkage isomers ?

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a

[Pd(P Ph3)2, (NCS)2], [Pd (P Ph3)2(SCN)2]

b

[Co(NH3)5NO3]SO4, [Co (NH3)5SO4]NO3

c

[PtCl2(NH3)4]Br2, [PtBr2 (NH3)4]Cl2

d

[Cu(NH3)4][PtCl4], [Pt(NH3)4][CuCl4]

answer is A.

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Detailed Solution

In [Pd(P Ph3)2, (NCS)2], [Pd (P Ph3)2(SCN)2] , NCS and SCN shows linkage isomerism, because ligand lone pair donate via S &N 

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