Which of the following pairs represents linkage isomers?

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$[Co {({NH}_{3})}_{5} {NO}_{3}] {SO}_{4}$ and $[Co {({NH}_{3})}_{5} ({SO}_{4})] {NO}_{3}$

$[Pd {({PPh}_{3})}_{2} (NCS)_{2}]$ and $[Pd {({PPh}_{3})}_{2} (SCN)_{2}]$

$[Cu {({NH}_{3})}_{4}] [Pt {Cl}_{4}]$ and $[Pt {({NH}_{3})}_{4}] [{CuCl}_{4}]$

$[Pt {({NH}_{3})}_{4} {Br}_{2}]$ and $[{PtBr}_{2} {({NH}_{3})}_{4}] {Cl}_{2}$

answer is A.

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Detailed Solution

$[Pd {({PPh}_{3})}_{2} (NCS)_{2}]$ and $[Pd {({PPh}_{3})}_{2} ({SCN}_{2}]$ are linkage isomers.

Linkage isomers are isomers with the same chemical formula but different arrangements of the ligand atom and the central metal atom.

Hence, option A is correct.

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