Q.

Which of the following pairs represents linkage isomers?

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a

CoNH35NO3SO4 and  CoNH35SO4NO3

b

PdPPh32(NCS)2 and  PdPPh32(SCN)2

c

CuNH34PtCl4 and  PtNH34CuCl4

d

PtNH34Br2 and PtBr2NH34Cl2

answer is A.

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Detailed Solution

PdPPh32(NCS)2 and PdPPh32SCN2are linkage isomers.

Linkage isomers are isomers with the same chemical formula but different arrangements of the ligand atom and the central metal atom.

Hence, option A is correct.

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