Q.

Which of the following pairs will show common ion effect?

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a

silver cyanide + potassium nitrite

b

barium chloride + barium sulphate

c

ammonium hydroxide + ammonium chloride

d

sodium chloride + hydrogen chloride

answer is C.

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Detailed Solution

Solution: Common ion effect is show when weak electrolyte and strong electrolyte is mixed. NH4OH  is weak base to which NH4Cl  is added which provides common NH4  ion dissociation of  NH4OH  is suppressed. Since  NH4OH  is a weak electrolyte whereas NH4Cl  is a strong electrolyte it shows the common ion effect.

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Which of the following pairs will show common ion effect?