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Q.

Which of the following point defect are shown by AgBr(s) crystals? 

i.Schottky defect

ii.Frenkel defect

iii.Metal excess defect

iv.Metal deficiency defect

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a

(ii) and (iii)

b

(iii) and (iv)

c

(i) and (ii)   

d

(i) and (iii)   

answer is A.

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Detailed Solution

AgBr shows both Schottky, as well as the Frenkel detect. In AgBr, both Ag+ and Br ions are absent from the lattice causing the Schottky defect. However, Ag+ ions are mobile so they have a tendency to move aside the lattice and trapped in interstitial site hence, cause, Frenkel defect.

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