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Q.

Which of the following property of Pb is due to the consequence of inert pair effect?
 

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a

 Higher stability of Pb4+ as compared to Pb2+

b

 Higher stability of Pb2+ as compared to Sn2+

c

 Size of Pb2+ is 133 but size of Pb4+ is 84

d

 Pb4+ has oxidising property

answer is B, D.

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Detailed Solution

Pb4+ can easily lose 2 electrons to produce Pb2+ and thus Pb4+ acts as an oxidising agent.

According to inert pair effect, Pb2+2 is more stable than Sn2+.

As the relative property to be in higher oxidation state of elements of same group, increases down the group.

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